Low-density SMC: Better living through chemistry

Proprietary sizing, special glass roving and microspheres strip 9 kilos of weight from Corvette body panels.
#adhesives #sheetmoldingcompound #generalmotors


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A new, low-density sheet molding compound (SMC), formulated and molded by Continental Structural Plastics (CSP, Auburn Hills, MI, US), is responsible for reducing mass by 9 kg on body panels for 2016 model year Chevrolet Corvette sports cars from General Motors Co. (GM, Detroit, MI, US). CSP calls the new material TCA (tough Class A) Ultra Lite. At a specific gravity (SG) of 1.2, it offers a 28% mass reduction vs. CSP’s mid-density TCA Lite (1.6 SG) grades, and a 43% reduction vs. conventional 1.9 SG grades of SMC. More importantly, TCA Ultra Lite not only offers mechanical performance comparable to TCA Lite (both feature a matrix of unsaturated polyester from AOC LLC, Collierville, TN, US), but also reportedly bonds more effectively to paint and adhesive. Although this first commercial use of TCA Ultra Lite is on painted Class A body panels, the company says it’s equally appropriate for fabrication of structural parts.

TCA Ultra Lite was introduced as a running change in the summer of 2015 to replace TCA Lite on all Corvette exterior body panels except the hood and roof, which are molded in carbon fiber-reinforced epoxy by another supplier. Notably, neither tooling, process adjustments nor part thickness changes were necessary during the material transition. “One day we were running TCA Lite, and the next day we were running TCA Ultra Lite,” explains Dr. Probir Guha, CSP’s VP, advanced R&D, “and there were no other changes.”


Aluminum is the real competition

Although the transition reportedly occurred without hiccups, the technology that made that smooth transition possible was five years in the making. Guha credits Frank Macher, who became CSP chairman in October 2010 and CEO in February 2011, with making TCA Ultra Lite’s invention possible.

“When he came on board, Frank said, ‘Stop everything and focus on R&D. Our competitor isn’t another composite, it’s aluminum,’” recalls Guha. “True to his word, he gave us the resources to dig deeper into the chemistry so we could under- stand what was going on at the molecular level.”

SMC already offered a host of benefits vs. steel and aluminum. It’s typically 40% lighter than metals in specification-comparable geometries. It also provides better low- and high-speed impact performance (energy management), so it brings safety benefits to vehicle occupants. Although it won’t rust or corrode and doesn’t need such treatment, it has the thermal and chemical resistance 
to survive the automotive electrophoretic (e-coat) deposition process used as a rust preventative on metallic chassis components. Hence, SMC parts can be attached to the body-in-white (the preferred assembly method) and don’t require special post e-coat assembly.

Far greater design flexibility is
another SMC advantage (especially
 vs. aluminum), and that’s a real boon
to automakers who favor the use
 of surfaces with compound curves,
 which are either difficult and costlyor impossible to duplicate in metals,
 owing to the deep draw. Parts-consoidation opportunities and insert 
molding enable previously multiple
 subcomponents to be molded as
 a single complex composite part,
 reducing the number of tools (dies) 
and post-mold assembly operations 
necessary to make the same part
 from metal. Even better, because it’s
 molded on compression presses, SMC
 offers this styling freedom at lower
 tooling costs than metals at both low
 and moderate production volumes
 (typically 50-70% tooling cost savings 
vs. steel or aluminum at build volumes 
of less than 150,000 per year). Historically, at higher volumes, the greater 
raw material cost of SMC vs. metals 
and the slower part production cycle 
cancel out SMC’s overall cost advantage: SMC takes 2.0-3.5 minutes vs. 
20-30 seconds for metals, despite the fact that that’s per die for a metal version of the part that requires multiple subcomponents, which need subsequent assembly. So the SMC molder must multiply the number of tools and machines to maintain competitive production rates at the higher volumes. This normally puts SMC out of the running in the per-part cost sweepstakes.

With aluminum as their target, CSP researchers focused on ways to make SMC cost-competitive at any production volume. The key was to target specific gravity: “We kept running the numbers and our calculations kept telling us that we could take on aluminum if we could get to 1.2,” explains Guha. “We got down to basics and started analyzing each component’s contribution.”

SMC typically contains resin, glass fiber, mineral filler and additives. One way the company reduced its product density was by replacing some percentage of its typical calcium carbonate (CACO3) filler with hollow glass microspheres (affectionately called “bubbles” in the industry). However,
 microspheres can crush easily during 
compounding or molding. “When that 
happened, our mechanicals would go
 south and our density would go up,”
recalls Guha. “We felt we needed both 
a tougher bubble and to do work on
the surface of the bubbles to improve 
interfacial adhesion.”


Chemistry is key

As luck would have it, part of the Macher-approved R&D investment included a state-of-the-art scanning electron microscope (SEM). Researchers lost no time mixing new formulations, molding and testing parts, then sectioning samples and looking at morphology via the SEM to try and understand how the structure they were seeing related to the performance they were measuring and the chemical tinkering they were doing. What they saw led to a three-pronged solution, and a number of different ways to improve the resin/reinforcement interface.

First, they looked at numerous types of microspheres, eventually switching to a tougher, higher performance microsphere from 3M (St. Paul, MN, US). Although CSP won’t divulge specifics, Guha does say the product has higher crush strength and has not been used previously in automotive composites applications with unsaturated polyester resins.
 Second, they strengthened the resin/ microsphere bond with a proprietary sizing that was developed and patented by CSP researchers, rather than using those offered by microsphere or additive suppliers. The sizing’s formulation is said to work with the free-radical reaction mechanism used in unsaturated polyester and vinyl ester. According to Guha, the difference between the new sizing and previous versions was “like night and day” — not only performance-wise, but also clearly visible on SEM images.

Serendipitously, as researchers dug deeper into the chemistry and physics of the resin/microsphere interface, they discovered that a longstanding issue with paint adhesion on certain SMC parts wasn’t the fault of a poor bond between paint and
 the surface of the composite, as everyone had assumed. SEM scans of part surfaces from which paint had flaked off revealed that not only the paint but the entire top layer of the composite’s resin matrix had detached from microsphere surfaces. CSP researchers discovered that their work on strengthening the resin/microsphere interface not only met or exceeded target mechanicals at lower density, the intended result, but also provided the additional benefit of improving the SMC’s capacity to bond well with paints and adhesives.

Third, researchers re-examined their options for glass rovings, selecting ME1975 multi-end glass roving, then newly formulated by Owens Corning (Toledo, OH, US) specifically for unsaturated-polyester SMC applications that require high strength and corrosion resistance. Here, too, the surface chemistry of this E-glass variant was the key contributor to performance improvements seen in surface finish and mechanicals.

Throughout the development process,
 as CSP researchers found something that seemed to improve performance, they evaluated the formulation not only by means
of standard, small-scale mechanical tests, but also with a lab-scale setup that simulated e-coat processing conditions. As
 their confidence grew with each formulation refinement, they took samples around to multiple automakers and did trials in OEM labs and factories. Eventually, with the formulation more or less set, they began looking for their first commercial application.


Vetting the technology

That first application, on GM’s flagship Corvette, now totals 21 body panel assemblies (depending on model), including doors, decklids (trunks), hatches, door surrounds, quarter panels, fenders, convertible tonneau assemblies, and coupé roof bows (read more online about how the the current Corvette also represents the first use of a new out-of-autoclave carbon composite production method in “Faster cycle, better surface: Out of the autoclave" under Editor's Picks at the right). The technology has fulfilled its promise to reduce costs vs. aluminum at all volumes: Life-cycle analyses done by CSP reportedly show that even at volumes as high as 350,000-400,000 vehicles per year, TCA Ultra Lite costs less per part than aluminum.

“In materials engineering, shaving off a single pound per car is a significant accomplishment,” notes Corvette chief engineer Tadge Juechter, “so saving 20 lb per car is monumental.”

Judges at two recent industry events seemed to agree. At CAMX 2015 in Dallas, TX, US, CSP won the conference’s Unsurpassed Innovation award. A month later, the SPE Automotive Division’s blue-ribbon judging panel selected TCA Ultra Lite as its Materials category and Grand Award winner as the year’s most innovative use of plastics at the 45th-annual SPE Automotive Innovation Awards Gala in Livonia, MI, US.

What’s next? Guha says the company is hard at work on new formulations of carbon fiber-reinforced SMC, as well as carbon composite prepreg and carbon material suitable for RTM. Key bogies are reducing offal, exploring the most efficient use of hybrid glass/ carbon reinforcement systems and finding a carbon-neutral way to recycle carbon fiber from scrap parts (that is, to
 recover fiber without burning).
 He predicts that in the not-too-
distant future, we’ll see carbon
 composites on high-volume,
moderate-cost vehicles, not just
 on high-cost, high-performance